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Kyaw M. Soe, Renman Ruan, Yan Jia, Qiaoyi Tan, Zhentang Wang, Jianfeng Shi, Chuangang Zhong, Heyun Sun (2021) Influence of jarosite precipitation on iron balance in heap bioleaching at Monywa copper mine. Journal of Mining Institute. Vol 247. p. 1-12. DOI: 10.31897/PMI.2020.1.11
SoeK. M., RuanR., JiaY., TanQ., WangZ., ShiJ., ZhongC., & SunH. (2021). Influence of jarosite precipitation on iron balance in heap bioleaching at Monywa copper mine. Journal of Mining Institute, 247, 1-12. https://doi.org/10.31897/PMI.2020.1.11

Influence of jarosite precipitation on iron balance in heap bioleaching at Monywa copper mine

Authors:
Kyaw M. Soe1
Renman Ruan2
Yan Jia3
Qiaoyi Tan4
Zhentang Wang5
Jianfeng Shi6
Chuangang Zhong7
Heyun Sun8
  • 1 — Ph.D. CAS Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences ▪ Orcid
  • 2 — Dr.Habil. CAS Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences ▪ Orcid
  • 3 — Dr.Habil. CAS Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences ▪ Orcid
  • 4 — Senior Researcher CAS Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences ▪ Orcid
  • 5 — Managing Director of Myanmar Yangtse Copper Ltd Wanbao Mining Ltd ▪ Orcid
  • 6 — General Manager of Myanmar Wanbao Mining Ltd Wanbao Mining Ltd ▪ Orcid
  • 7 — начальник инженерного отдела Wanbao Mining Ltd ▪ Orcid
  • 8 — Senior Researcher State Key Laboratory of Biochemical Engineering Institute of Process Engineering, Chinese Academy of Sciences ▪ Orcid
Date submitted:
2020-06-10
Date accepted:
2020-11-19
Date published:
2021-05-21

Abstract

Ferric iron is an important oxidant in sulfide ore bioleaching. However, recirculating leach liquors leads to excess iron accumulation, which interferes with leaching kinetics and downstream metal recovery. We developed a method for controlling iron precipitation as jarosite to reduce excess iron in heap bioleaching at Monywa copper mine. Jarosite precipitation was first simulated and then confirmed using batch column tests. From the simulations, the minimum pH values for precipitation of potassium jarosite, hydronium jarosite, and natrojarosite at 25 °C are 1.4, 1.6, and 2.7, respectively; the minimum concentrations of potassium, sulfate, ferric, and sodium ions are 1 mM, 0.54, 1.1, and 3.2 M, respectively, at 25 °C and pH 1.23. Column tests indicate that potassium jarosite precipitation is preferential over natrojarosite. Moreover, decreased acidity (from 12 to 8 g/L), increased temperature (from 30 to 60 °C), and increased potassium ion concentration (from 0 to 5 g/L) increase jarosite precipitation efficiency by 10, 5, and 6 times, respectively. Jarosite precipitation is optimized by increasing the irrigating solution pH to 1.6. This approach is expected to reduce the operating cost of heap bioleaching by minimizing the chemicals needed for neutralization, avoiding the need for tailing pond construction, and increasing copper recovery.

Keywords:
jarosite precipitation thermodynamics column bioleaching iron balance Monywa copper mine
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